Technical Data Sheet
Eastman Tritan™ Renew Copolyester EX401-25

Applications Baby bottles/sippy cups Childcare items Infant/toddler

Key Attributes Chemical resistance Clarity Global food contact regulatory clearances Heat resistance Hydrolytic stability Impact resistance Processing ease Sterilization capable via steaming or boiling water

Product Description
Tritan™ Renew copolyester EX401-25, specifically developed for the Infant Care market, is an amorphous copolyester with excellent appearance and clarity. Tritan Renew EX401-25 contains a mold release derived from vegetable based sources. Its most outstanding features are clarity, excellent toughness, hydrolytic stability, and heat and chemical resistance. Tritan Renew EX401-25 meets infant care sterilization requirements via boiling water or microwave steam sterilization. This new-generation copolyester can also be molded into various applications without incorporating high levels of residual stress. Combined with Tritan's outstanding chemical resistance and hydrolytic stability, these features give molded products enhanced durability in the dishwasher environment, which can expose products to high heat, humidity, and aggressive cleaning agents.

Tritan Renew EX401-25 can be converted into parts using injection molding, injection stretch blow molding (ISBM), and extrusion blow molding techniques.

Tritan Renew EX401-25 may be used in repeated use food contact articles under United States Food and Drug Administration (FDA) regulations. Contact Eastman representative for details on global food contact regulatory clearances.

Tritan Renew EX401-25 is included in Eastman Chemical Company’s Customer Notification Procedure which details our policy for customer notification when significant changes are made in Tritan Renew EX401-25 sold into the infant care market. This procedure provides the infant care industry an added layer of confidence in the consistent quality and performance of Tritan™

Eastman Renew polymers have been certified by International Sustainability & Carbon Certification (ISCC), a global, independent agency for tracking sustainable content in a variety of industries. Renew polymers are produced with ISCC certified circular content by mass balance allocation.

Renew polymers enable a brand to reduce consumption of fossil feedstock-based plastics, achieve sustainability targets without compromise, and be a fast mover in a growing market for sustainable consumer products.

Typical Properties

Propertya	Test Methodb	Typical Value, Unitsc
General Properties
Specific Gravity	D 792	1.17
Injection Mold Shrinkage	D 955	0.005-0.007 mm/mm (0.005-0.007 in./in.)
ISBM Blow Mold Shrinkagee	EMN	0.012-0.016 mm/mm
ISBM Bottle Properties
Fill Volume Shrinkage - Boiling, 1 hrd	EMN	<1 %
Fill Volume Shrinkage - Boiling, 2 hrd	EMN	<1.5 %
Fill Volume Shrinkage - Dishwasherd	EMN	<1 %
Microwave Steam Sterilization (Total Energy=Wattage*Minutes)d	EMN	Up to 11,200 W-min
Microwave Boiling, Oven Powerd	EMN	Up to 2200 W
Thermal Shock, Water Immersion, 98 C to 35 Cd	EMN	No effect
Mechanical Properties (ISO Method)
Tensile Strength @ Yield	ISO 527	45 MPa
Tensile Strength @ Break	ISO 527	49 MPa
Elongation @ Yield	ISO 527	7 %
Elongation @ Break	ISO 527	130 %
Tensile Modulus	ISO 527	1624 MPa
Flexural Modulus	ISO 178	1531 MPa
Izod Impact Strength, Notched
@ 23°C	ISO 180	66 kJ/m2
@ -40°C	ISO 180	14 kJ/m2
Mechanical Properties
Tensile Stress @ Yield	D 638	44 MPa (6400 psi)
Tensile Stress @ Break	D 638	53 MPa (7700 psi)
Elongation @ Yield	D 638	7 %
Elongation @ Break	D 638	140 %
Tensile Modulus	D 638	1585 MPa (2.28 x 105 psi)
Flexural Modulus	D 790	1585 MPa (2.28 x 105 psi)
Flexural Yield Strength	D 790	66 MPa (9600 psi)
Rockwell Hardness, R Scale	D 785	115
Izod Impact Strength, Notched
@ 23°C (73°F)	D 256	650 J/m (12.2 ft·lbf/in.)
@ -40°C (-40°F)	D 256	126 J/m (2.4 ft·lbf/in.)
Impact Strength, Unnotched
@ 23°C (73°F)	D 4812	NB
@ -40°C (-40°F)	D 4812	NB
Impact Resistance (Puncture), Energy @ Max. Load
@ 23°C (73°F)	D 3763	59 J (43 ft·lbf)
@ -40°C (-40°F)	D 3763	63 J (46 ft·lbf)
Optical Properties
Total Transmittance	D 1003	92 %
Haze	D 1003	<1 %
Properties After Boiling
Haze
After 8 hr boiling	EMN	<1 %
Izod Impact Strength, Notched, 23 C
After 8 hr boiling	EMN	650 J/m
After re-equilibration		643 J/m
Tensile Stress @ Yield
After 8 hr boiling	EMN	44 MPa
After re-equilibration		45 MPa
Elongation @ Yield
After 8 hr boiling	EMN	7 %
After re-equilibration		6.5 %
Thermal Properties
Deflection Temperature
@ 0.455 MPa (66 psi)	D 648	109 °C (228 °F)
@ 1.82 MPa (264 psi)	D 648	92 °C (198 °F)
Typical Drying Conditions
Drying Temperature		88 °C (190 °F)
Drying Time		4-6 hrs
Dewpoint		< -35 °C (< -30 °F)
Typical Processing Conditions - Extrusion Blow Molding (EBM)
Processing Melt Temperature		240-250 °C (465-480 °F)
Mold Temperature		25-45 °C (80-110 °F)
Typical Processing Conditions - Injection Molding
Processing Melt Temperature		260-282 °C (500-540 °F)
Mold Temperature		38-66 °C (100-150 °F)
Typical Processing Conditions - Injection Stretch Blow Molding (ISBM)
Processing Melt Temperature		270-285 °C (520-545 °F)
Injection Mold Temperature		60-70 °C (140-160 °F)
Preform Temperature at Blow		185-195 °C (365-385 °F)
Primary Blow Pressure		0.03-0.08 MPa (4-12 psi)
Secondary Blow Pressure		0.2-0.3 MPa (25-40 psi)
Blow Mold Temperature		80-90 °C (175-195 °F)
Residual Stress Under Polarized Light, Fringe Count	EMN	<= 3

^aUnless noted otherwise, all tests are run at 23°C (73°F) and 50% relative humidity.
^bUnless noted otherwise, the test method is ASTM.
^cUnits are in SI or US customary units.
^dProperties are typical of bottles made with proper processing to minimize residual stress.
^eApplies to the stretch blow molded portion only (not the injection molded preform).



Technical Disclaimer
Eastman makes no representation and disclaims any warranty that the material in any particular shipment will conform exactly to the values given.  Values as well as the performance of the final molded article may be affected by various factors such as the part design, mold design or tooling,  drying, processing conditions as well as coloring or pigmentation of the product. No warranty of merchantability or fitness for use is made, and nothing herein waives any of the Seller''s conditions of sale. You must make your own determination of the suitability of this product in your specific application due to the many factors (e.g. design, processing and conditions of use) that affect the performance of the final molded article.  Suitability of use should be evaluated with appropriate testing and analysis. The processing melt temperature and mold temperature refer to the actual resin melt temperature and actual mold surface temperature respectively. Consider overall resin residence time, part shot size utilization and part geometry to set appropriate processing melt temperature and mold temperature in order to minimize IV loss and maximize molded part performance.


Comments
Properties reported here are based on limited testing. Eastman makes no representation that the material in any particular shipment will conform exactly to the values given.

---

Eastman and its marketing affiliates shall not be responsible for the use of this information, or of any product, method, or apparatus mentioned, and you must make your own determination of its suitability and completeness for your own use, for the protection of the environment, and for the health and safety of your employees and purchasers of your products. No warranty is made of the merchantability of fitness of any product, and nothing herein waives any of the Seller's conditions of sale.

9/7/2021 3:15:40 PM